Abstract
A theoretical model has been developed to explain at the electronic level the charge-transfer-induced spin transition (CTIST) in crystals based on cyano-bridged binuclear Fe-Co clusters. The CTIST is considered as a cooperative phenomenon (phase transformation) driven by the long-range electron-deformational interaction via the acoustic phonons field that is taken into account within the mean field approach. The model for CTIST includes also the metal-metal electron transfer and intracluster magnetic exchange. The conditions that favor the CTIST are discussed. The qualitative explanation of the experimental data is given.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
