Abstract
Abstract The charge-transfer transition between ion radical molecules is known to take place in solid ion radical salts. The present paper describes some spectroscopic features of the charge-transfer absorptions observed in complex anion radical salts of (Cs+)2(TCNQ)3\ewdot\ewdot and (Morpholinium+)2(TCNQ)3\ewdot\ewdot. A one-dimensional Hubbard model consisting of equivalent sites with less than half-occupied orbitals was applied to those systems in order to explain the transition energy and the line shape of the charge-transfer absorptions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.