Charged Boron Nitride Nanosheet Membranes for Improved Organic Solvent Nanofiltration.

Abstract

Two-dimensional nanomaterial-based membranes have earned broad attention because of their excellent capability of separation performance in a mixture that can challenge the conventional membrane materials utilized in the organic solvent nanofiltration (OSN) field. Boron nitride (BN) nanosheet membranes have displayed superb stability and separation ability in aqueous and organic solutions compared to the widely researched analogous graphene-based membranes; nevertheless, the concentration polarization of organic dye pollutants fades their separation performance and eclipses their potential adoption as a feasible technology. Herein, PDDA-modified BN (PBN) and sodium alginate-modified BN (SBN) nanosheet membranes with a thinner laminar structure are facially fabricated to improve the molecule separation performance compared to that of the pristine BN membrane. In aqueous separation application, the SBN membranes (2 μm) can reject positively charged dyes up to 100% and the PBN membrane (2 μm) could reject negatively charged dyes up to 100%. Impressively, the PBN membranes (3 μm) and SBN membranes (3 μm) demonstrate record high performances in OSN, with a permeance of 809 L m-2 h-1 bar-1 and 97.71% rejection to acid fuchsin in acetonitrile and 290 L m-2 h-1 bar-1 and 94.94% rejection to Azure B in dimethyl sulfoxide, respectively. The charged PBN and SBN nanosheet membranes demonstrate stable separation capability, exhibiting their potential for practical water and organic solvent purification processes.