Abstract

These studies are devoted to electrical and electrochemical investigations of cobalt-doped manganese spinel. The studies of electrical conductivity and thermoelectric power in the wide temperature range (220–1090 K) in relation to oxygen nonstoichiometry together with the behaviour of the material in Li/Li +/Li x Co y Mn 2− y O 4 cell enable to determine electronic defect structure of the LiCo y Mn 2− y O 4 cathode material.

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