Abstract
Mulliken's early work on the magnitudes of charge-transfer transition moments and on their nuclear-coordinate dependences is of fundamental importance for an understanding of the magnitudes, anisotropies and nuclear-coordinate dependences of molecular polarizabilities and hence of dispersive intermolecular interactions. His prediction of large two-electron charge-resonance transition moments between excited states of ionic character at large internuclear distances is consistent with detailed ab initio results for the hydrogen molecule in which the interaction between ionic and excited neutral configurations generates interesting additional structures in the pattern of electronic energy curves and transition moments.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
