Abstract
AbstractCharge transfer in adsorbate‐substrate systems has been studied in the limiting case of an unperturbed substrate extending the Anderson‐Newns treatment to two‐ and three‐dimensional substrates. This allows comparison of different chemisorption sites within an essentially analytic treatment. Important changes of the local densities of states with respect to the usual one‐dimensional model are obtained. The resulting charge transfers are of the same order of magnitude as those obtained by adding correlation effects to the one‐dimensional Anderson‐Newns model.
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