Abstract
Charge-transfer interactions between aromatic amines and s-trinitrobenzene have been utilized for the distinction and determination of some primary, secondary, and tertiary aromatic amines. Charge-transfer (CT) band maxima of the complexes show red shifts in passing from primary → secondary → tertiary amines. Beer's law was obeyed at the respective CT band maximum and the results of determinations of pure amine samples as well as of their binary, ternary, and quaternary mixtures are described. Compounds containing both donor and acceptor groups cannot be determined by the recommended procedure.
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