Charge Transfer and Recombination Dynamics at Inkjet-Printed CuBi2O4 Electrodes for Photoelectrochemical Water Splitting

Abstract

One of the principal challenges for solar-driven hydrogen production via water splitting is to improve the solar-to-hydrogen conversion efficiency. We have employed combinatorial chemistry using a materials inkjet printer, and selected CuBi2O4 as a promising p-type material. The steady-state photocurrent corresponding to water reduction for a 280 nm film at 0.2 V (RHE) was about 0.12 mA cm–2, significantly lower than that attainable for a 2 eV band gap semiconductor. We have applied intensity-modulated photocurrent spectroscopy (IMPS) to distinguish between the photoelectrochemical processes involved and to determine the associated time constants, in order to gain insight into the loss processes responsible for the low efficiency. The charge separation efficiency reaches up to 0.66 at sufficiently negative potential, however, the recombination rate constant is larger than that corresponding to electron transfer to the solution. This results in a relative charge transfer efficiency of 0.2–0.4, explaining t...