Abstract
Through careful consideration of charge matching, a simple replacement of metal ion from Cd(2+) to Ln(3+) in a building unit successfully transforms an anionic microporous framework into a series of isostructural porous neutral heterometallic frameworks [Cd(3)Ln(2)(btc)(4)(H(2)O)(6)(dmf)(4)]·x(solvent) (1; Ln=Tb, Eu, Nd, Gd, Sm, dmf=N,N'-dimethylformamide) by employing five different lanthanide ions. 1-Tb and 1-Eu exhibit interesting photoluminescent properties, and remarkably, 1-Tb can act as a luminescent sensor to identify organic solvents and metal ions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
