Charge and Discharge Behaviour of Li-Ion Batteries at Various Temperatures Containing LiCoO2 Nanostructured Cathode Produced by CCSO

Y.Y Mamyrbayeva,K.S Martirosyan,S.E Kumekov,R.E Beissenov,M.A Hobosyan

doi:10.18321/ectj235

Abstract

<p>There are technical barriers for penetration market requesting rechargeable lithium-ion battery packs for portable devices that operate in extreme hot and cold environments. Many portable electronics are used in very cold (-40 °C) environments, and many medical devices need batteries that operate at high temperatures. Conventional Li-ion batteries start to suffer as the temperature drops below 0 °C and the internal impedance of the battery increases. Battery capacity also reduced during the higher/lower temperatures. The present work describes the laboratory made lithium ion battery behaviour features at different operation temperatures. The pouch-type battery was prepared by exploiting LiCoO<sub>2</sub> cathode material synthesized by novel synthetic approach referred as Carbon Combustion Synthesis of Oxides (CCSO). The main goal of this paper focuses on evaluation of the efficiency of positive electrode produced by CCSO method. Performance studies of battery showed that the capacity fade of pouch type battery increases with increase in temperature. The experimental results demonstrate the dramatic effects on cell self-heating upon electrochemical performance. The study involves an extensive analysis of discharge and charge characteristics of battery at each temperature following 30 cycles. After 10 cycles, the battery cycled at RT and 45 °C showed, the capacity fade of 20% and 25% respectively. The discharge capacity for the battery cycled at 25 °C was found to be higher when compared with the battery cycled at 0 °C and 45 °C. The capacity of the battery also decreases when cycling at low temperatures. It was important time to charge the battery was only 2.5 hours to obtain identical nominal capacity under the charging protocol. The decrease capability of battery cycled at high temperature can be explained with secondary active material loss dominating the other losses.</p>

Highlights

Over the past 20 years, rechargeable lithium-ion battery technologies have evolved, providing increasingly greater energy density, greater energy per volume, longer cycle life, and improved reliability
One of the important issues is the significantly reduced energy and power capabilities of lithiumion batteries due to unwanted chemical or physical changes during the battery operation. Another problem is the loss of the active materials when batteries operate at low or high temperatures [2]
In this report we explore a novel method referred as Carbon Combustion Synthesis of Oxides (CCSO) to rapidly produce high-purity, nanoscale powders of lithium cobaltate (LiCoO2)

Summary

Introduction

Over the past 20 years, rechargeable ( known as secondary) lithium-ion battery technologies have evolved, providing increasingly greater energy density, greater energy per volume, longer cycle life, and improved reliability. One of the important issues is the significantly reduced energy and power capabilities of lithiumion batteries due to unwanted chemical or physical changes during the battery operation. Another problem is the loss of the active materials when batteries operate at low or high temperatures [2]. These changes are usually irreversible and they affect the electrical performance of the electrochemical cells. Battery manufacturers of battery-powered products usually design and produce products to deliver specified performance characteristics in a safe manner under expected usage conditions

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