Abstract
The reactions of title ylide (C 6 H 5 ) 3 PCHCOC 6 H 5 , (BPPY) and (n-C 4 H 9 ) 3 PCHCOC 6 H 5 , (BBuPY) with rhodium (III) and ruthenium (III) chloride in equimolar ratios using methanol as solvent have yielded crystals of [(BPPY-H) 3 Rh], ( 1 ), [(BPPY) 2 Ru(MeOH) 2 (H 2 O) 2 ]Cl 3 , ( 2 ), and [Ru(BBuPY)Cl 2 S 2 ]Cl (S = H 2 O or CH 3 OH), ( 3 ). The IR and 1 H, 13 C, 31 P NMR data of the products were obtained. Analytical and NMR data are consistent with the cyclometalated and octahedral structures for ( 1 ) and ( 2 ) respectively.
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