Characterization of Water-Soluble Intermediates from Slow Pyrolysis of Cellulose at Low Temperatures

Abstract

This study reports the presence of both sugar and anhydro-sugar oligomers of a wide range of degrees of polymerization (1–10) as water-soluble intermediates in the solid residues produced from cellulose slow pyrolysis at low temperatures (100–350 °C) and a holding time of 30 min. These sugar and anhydro-sugar oligomers appear to be important precursors of volatiles formation during cellulose pyrolysis. Even at very low pyrolysis temperatures (e.g., 100 °C), sugar oligomers are found in the water-soluble intermediates. As the breakage of glycosidic bonds within cellulose chains is unlikely to take place under such low-temperature conditions, the results suggest that such sugar oligomers are likely to be produced from the short glucose chain segments that are hinged with crystalline cellulose via weak bonds (e.g., hydrogen bonds) in amorphous portions of microcrystalline cellulose. As the pyrolysis temperature increases, a wide range of anhydro-sugar oligomers start to appear while the sugar oligomers start...