Characterization of water migration behavior during spontaneous imbibition in coal: From the perspective of fractal theory and NMR

Abstract

The spontaneous imbibition (SI) of water plays a crucial role in determining the wetting effect of water injection in coal seams. It is significant to investigate the flow behavior of water in coal during the SI. Contact angle measurement, SI experiment, and low-field nuclear magnetic resonance (LF-NMR) tests have been conducted to measure the properties of coal from different regions of China. The mass change of the coal by SI is related to the square root of time divided into three-stage linear functions in which the slope represents the imbibition rate of coal. The imbibition rate decreases with the increased SI time. The contact angle of bituminous coal is smaller than that of anthracite and is negatively proportional to the SI rate and capacity index C. Water is primarily stored in the adsorption and seepage pores, and little in microfractures. It shows that the fractal dimensions of the partial free pore (Db) and total pores (D) decline in a form of power law, while the fractal dimension of the free pore (Dz) declines irregularly. D-10 and D10 are strongly linear with the T2 spectrum area of adsorption pores, seepage pores, and microfractures, respectively. It indicates that the low-probability measurement area can represent the adsorption pores, and high-the probability measurement area represents seepage pores and microfractures. Adsorption pores play an important role during SI (DSI). The difference between the amplitude increments of adsorption pore and that of seepage pores/microfractures is the key factor affecting multifractal parameters of T2 spectra. The linear relationship between H and Db reveals that water preferentially enters a pore with lower roughness and better connectivity DSI. The process of SI has been divided into three stages in terms of SI rate. The transport process of water within the coal at different stages has been discussed as well. The results of this work are of great significance for optimizing the coal seam water injection and reducing the risk of underground coal mine disasters.