Abstract

Environmental problems have been associated with energy consumption and waste management. A solution is the development of renewable materials such as organic phase change materials. Characterization of new materials allows knowing their applications and simulations provide an idea of how they can developed. Consequently, this research is focused on the thermal and chemical characterization of five different avocado seed oils depending on the maturity stage of the seed: 100% unripe, 25% mature-75% unripe, 50% mature-50% unripe, 75% mature-25% unripe, and 100% mature. The characterization was performed by differential scanning calorimetry, Fourier transform infrared spectroscopy, and thermogravimetric analysis. The best oil for natural environments corresponded to 100% matured seed with an enthalpy of fusion of 52.93 , and a degradation temperature between 241–545 °C. In addition, the FTIR analysis shows that unripe seed oil seems to contain more lipids than a mature one. Furthermore, a simulation with an isothermal box was conducted with the characterized oil with an initial temperature of −14 °C for the isothermal box, −27 °C for the PCM box, and an ambient temperature of 25 °C. The results show that without the PCM the temperature can reach −8 °C and with it is −12 °C after 7 h, proving its application as a cold thermal energy system.

Highlights

  • Part of the world’s development depends on technological advances in energy, but economic growth has brought an increase in energetic consumption where fossil fuels represent about 81% of the total

  • We planned to record a spectral range between 400 to 4000 cm−1, the Differential Scanning Calorimetry (DSC) recorded signals between the range of 750 to 3000 cm−1. It can be seen common bands mainly associated to the recognizable lipids for the stretch and intense peaks which confirms that they are the oils [62]

  • By analyzing the Fourier Transformed Infrared Spectroscopy (FTIR) study results it was possible to identify peaks that represent the presence of lipids which confirms that the extraction of the avocado seed oil was effective

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Summary

Introduction

Part of the world’s development depends on technological advances in energy, but economic growth has brought an increase in energetic consumption where fossil fuels represent about 81% of the total. An important part of solving the environmental waste problem is managing agricultural waste. In this sense, optimization of processes like isolation of biophenols from olive leaf waste leads to a 61% ecological reduction and a 49% mitigation of the carbon footprint [5]. Thermal energy storage (TES) makes efficient use of fuels and renewable sources. Phase change materials (PCMs) are materials that use LHS. The main feature of these materials is the storage or release of great amounts of energy to maintain their temperature when a phase change takes place [7]. It must be considered that the materials that are commonly used in latent heat applications are costly and produced from non-renewable materials, mainly derived from the petrochemical industry, but these types of compounds can be made from cheap, renewable, raw materials, such as animal fats and vegetable oils [8]

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