Characterization of Type-II Acetylated Cellulose Nanocrystals with Various Degree of Substitution and Its Compatibility in PLA Films.

Feng Dong,Chunde Jin,Shujun Li,Meiling Yan

doi:10.3390/polym9080346

Feng Dong, Chunde Jin + Show 2 more

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https://doi.org/10.3390/polym9080346

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Abstract

In order to decrease the self-agglomeration and improve the hydrophobic properties of type-II acetylated cellulose nanocrystals (ACNC II), various degree of substitution (DS) values of ACNCs were successfully prepared by a single-step method from microcrystalline cellulose with anhydrous phosphoric acid as the solvent, and acetic anhydride as the acetylation reagent, under different reaction temperatures (20–40 °C). To thoroughly investigate the DS values of ACNC II, analyses were performed using Fourier transform infrared spectroscopy (FT-IR), 13C cross polarization-magic angle spinning (CP-MAS) nuclear magnetic resonance (NMR), and X-ray photoelectron spectroscopy (XPS). At a reaction temperature of 40°C, the highest DS value was successfully obtained. XRD proved that the crystal structure of ACNC II with various DS values was maintained after acetylation. TEM showed the threadlike shape for ACNC II with various DS values. The ACNC II with various DS values was introduced into a polylactic acid (PLA) matrix to produce PLA/ACNC composite films, which showed improved rheological and thermal properties. This improvement was primarily attributed to good dispersion of the ACNC II, and the interfacial compatibility between ACNC II and the PLA matrix. This study aims to analyze the compatibility of ACNC II with various DS values in the PLA matrix by microstructure, crystallization, and rheological and thermal tests.

Highlights

Nowadays, cellulose nanocrystals (CNCs) have attracted considerable attention because of their valuable properties, such as high mechanical properties, stiffness, and surface area [1]
This improvement was primarily attributed to good dispersion of the acetylated cellulose nanocrystals (ACNCs) II, and the interfacial compatibility between ACNC II and the polylactic acid (PLA) matrix
This study aims to analyze the compatibility of ACNC II with various degree of substitution (DS) values in the PLA matrix by microstructure, crystallization, and rheological and thermal tests

Summary

Introduction

Cellulose nanocrystals (CNCs) have attracted considerable attention because of their valuable properties, such as high mechanical properties, stiffness, and surface area [1]. Cellulose I is natural cellulose from different sources. Cellulose II can be obtained from cellulose I by mercerization or regeneration [3]. Unlike cellulose I, cellulose II has an antiparallel strand arrangement and monoclinic lattice arrangement, so the intermolecular hydrogen bonding is more complicated in cellulose II compared with cellulose I [7]. Apart from the hydrogen bonds, cellulose II has its glucopyranose rings stacked with each other by hydrophobic interactions along the (1-10) plane, thereby resulting in an increased density of hydroxyl groups on the surface, which leads to increased hydrophilicity [8]. The CNC II particles often aggregate due to the Polymers 2017, 9, 346; doi:10.3390/polym9080346 www.mdpi.com/journal/polymers

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