Year-end Sale % OFF 
Abstract
Two-dimensional (2D) correlation analysis has been applied to temperature-dependent FTIR spectra of Langmuir–Blodgett (LB) and spin-coated films of poly( tert-butyl methacrylate) (PtBMA). Synchronous 2D correlation spectra were generated for two temperature regions, i.e. those below and above the glass transition temperature ( T g), to investigate the re-orientation of polymer chain. The autocorrelation analysis revealed that the re-orientation of the bb C C O and bb C C O bonds connected to chain backbone (bb) and that of the CO bond of the tert-butoxy group are significant below and above the glass transition temperature, respectively. It is implied strongly from these observations that the simultaneous re-orientation of the chain backbone and the side chain is responsible for the β-transition of PtBMA.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
