Abstract

Natural rubber (NR) has excellent mechanical properties due to its unique molecular chain structure. In previous studies, the signal of the cis- and trans-isoprene units was deduced by 13C-NMR spectrum of the low molecular weight fraction of NR. In this study, through investigating the 1H-NMR spectra of ribbed smoked sheet 1 (RSS-1) and standard Chinese rubber whole fraction (SCR-WF), and Eucommia ulmoides gum (EUG), trans-1,4-polyisoprene (TPI), found that the methyl-proton in the cis- and trans-isoprene units in 1H-NMR spectra of NR showed signals at 1.61 and 1.53 ppm, respectively. Further, the content of trans-structure in the molecular chain of NR of different producing areas was calculated. The results show that the content of trans-structure in the molecular chain structure of RSS-1 and SCR-WF were 1.500 and 1.054%, respectively.

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