Abstract

The phenolic fraction of two coal-derived liquids has been isolated prior to high-resolution liquid chromatography and spectral characterization. Over 70 high-molecular-weight compounds were separated, in each case, with a slurry-packed capillary column. Off-line mass spectrometry and on-line miniaturized fluorescence spectroscopy were used for peak characterization. Two- to five-ring structures, with a high degree of alkylation or heteroatomic features, are suggested.

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