Characterization of the inverted metamorphic gradient of the Passos Nappe (SE-Brazil) based on multiple geothermobarometers

Abstract

Inverted metamorphic gradients are recognized in several Proterozoic to Phanerozoic orogens. However, the mechanisms that are responsible for the formation of these gradients are still a matter of discussion. In the southern Brasília Orogen, an inverted metamorphic gradient is recorded in the Passos Nappe, that comprises a sequence of metasedimentary rocks with minor intercalations of tholeiitic metamafic rocks, metamorphosed under greenschist facies (biotite zone) at the bottom and high-pressure granulite facies at the top. This paper presents a detailed investigation of pressure and temperature conditions along the Passos Nappe by integrating conventional geothermobarometry in metamafic rock and single-trace elements geothermometry (Zr-in-rutile and Ti-in-quartz) in quartzite. Nine lithostratigraphic units are identified in the Passos Nappe, which are informally named A to I, from the bottom to top, adding up to a minimum thickness of 4.56 km. In mafic rocks, the increase of metamorphic conditions is indicated by: (1) chemical variation of amphiboles, from actinolite/edenitic hornblende in Unit C, to pargasitic hornblende in Units E and G, and Fe-pargasite in Units H and I; (2) plagioclase composition varying from An1-13 in Unit C, An15-27 in Unit D to andesine at upper units; and (3) occurrence of clinopyroxene from the top of Unit E upwards. Additional petrographic features in quartzite also corroborate these insights, such as: the increase of grain size of both quartz and rutile, from bottom to top; the morphology of rutile crystals; the mechanism of quartz recrystallization (subgrain rotation dominates in lower units while grain boundary migration dominates in upper units) and the occurrence of rutile needles in quartz in the upper units, which suggest a continuous gradient. Combined application of Zr-in-rutile and Ti-in-quartz geothermometers in quartzite provided the following average temperature and pressure values for each unit: 673 °C and 11.7 kbar for Unit E, 690 °C and 9.5 kbar for Unit G, 747 °C and 11.6 kbar for Unit H and 758 °C and 11.3 kbar for Unit I. Our data indicate that the Zr-in-rutile and Ti-in-quartz systems do not re-equilibrate in metamorphic conditions lower than 600 °C. The extrapolation of these results to the low-grade units indicate: 496 °C and 4.8 kbar at Unit A, 504 °C and 4.8 kbar at Unit B, 502 °C and 4.4 kbar at Unit C. The results obtained with the geothermometer hornblende-plagioclase and the geobarometer garnet-rutile-ilmenite-plagioclase-quartz in metamafic rocks yielded the following average values for each unit: 486 °C and 5.0 kbar at Unit C, 568 °C and 6.0 kbar at Unit D, 622 °C and 8.1 kbar at Unit E, 650 °C and 8.4 kbar at Unit G, 743 °C and 9.4 kbar at Unit H and 723 °C and 11.2 kbar at Unit I. Since the two geothermobarometric approaches are based on independent chemical systems, the results obtained represent robust estimates for the temperature and pressure conditions for the inverted metamorphic gradient of the Passos Nappe. Comparing the inverted metamorphic gradient at the Passos Nappe with classical occurrences at the Himalaya Orogen, it is possible to assume that both origins were similar, which probably involved isotherm inversion due to subduction, channel flow process associated with shear heating and transport of higher pressure rocks over low-pressure rocks by reverse ductile shearing.