Characterization of the frayed edge site of micaceous minerals in soil clays influenced by different pedogenetic conditions in Japan and northern Thailand

Abstract

Radiocesium interception potential (RIP), a quantitative index of a frayed edge site of micaceous minerals, was investigated on test clay minerals (illite, kaolinite, montmorillonite and vermiculite) and soil clays formed under different pedogenetic conditions in the Kinki district of Japan and in northern Thailand to elucidate the effect of pedogenetic weathering on the amount of frayed edge site of micaceous minerals. A frayed edge site is defined as the wedge-shaped intermediate zone between non-expansible (1.0 nm) and hydrated (1.4 nm) interlayers, on which Cs is selectively adsorbed. The test clay minerals demonstrated unique RIP values closely associated with their charge characteristics. Very small RIP in non-micaceous test minerals (0.006 mol kg−1 in kaolinite; 0.1 mol kg−1 in montmorillonite) supported the fact that negative charges in these minerals do not show selective adsorption of 137Cs. Large RIP values in vermiculite (25.9 mol kg−1) compared with illitic minerals (4.3 mol kg−1 in silt size; 11.8 mol kg−1 in clay size) suggested that the frayed edge site increased as the expanded layer formed in the micaceous minerals. In northern Thailand soil clays, the absence of a vermiculitic expanded layer was indicated. Periodic wet–dry conditions may restrict K depletion from micaceous minerals in the region. It is concluded that micaceous minerals were weathered without layer expansion and, therefore, the amount of the frayed edge site was regulated by the content of micaceous minerals in northern Thailand. In Japanese soil clays, large RIP values were found in the EB and Bs horizons of a Podzodic profile (SW1), which had large vermiculitic expanded layers like the test vermiculite. However, the RIP values drastically decreased from the Bs to E horizon, maintaining a high vermiculitic layer charge. Thus, intensive weathering in highly acidic soils in Japan might reduce the frayed edge site.