Abstract
Crystals that result from the electrocrystallization of a 1:1 mixture of the organic donor molecules ET and MET with the I 3- anion are superconducting at ambient pressure, T c = 4.6 K. Single crystal X-ray diffraction investigations (298 K) show that the crystals are ß-(ET) 2I 3 and little or no MET is incorporated. However, at 125 K no modulated structure is observed, instead the ethylene groups of the ET molecule are ordered. The conformation of the ET molecule is the same as that observed in ß ∗-(ET) 2I 3, the high pressure form of ß-(ET) 2I 3, with T c ∼ 8 K.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
