Characterization of the Alkali and Hydrolysis Resistance of Polymer-Impregnated, Alkali-Resistant Glass Filaments.

Abstract

The aim of this series of tests was to characterize the alkali and water resistance of alkali-resistant (durability) glass filaments, which were optimized with two non-vulcanized formulations based on co-polymerizing styrene-butadiene rubbers (CemFil-SBR1 and CemFil-SBR2). Furthermore, it was assessed which of the two polymer-impregnated multifilament yarns is the better alternative for use in cementitious binders. For this purpose, the impregnated multifilament yarns were chemically conditioned for up to twelve months at temperatures of 23 and 50 °C in 2.5 percent sodium hydroxide solution and 2.5 percent potassium hydroxide solution as well as in 3 percent salt and distilled water. The samples were then subjected to material science tests. The liquid absorption capacities and the changes in the mass of the composite materials were determined at different times during conditioning. The load-bearing capacity of the samples was also tested using uniaxial fiber strand tensile tests. The durability of the polymer-impregnated multifilament yarns was described in detail in conjunction with scanning electron microscopy images and nominal cross-section determinations. The test liquids caused a reduction in strength during the storage period, which was accelerated by increased temperatures. The reduction in strength is mainly due to glass corrosion of the filaments. Glass corrosion is delayed due to the good impregnation quality, which fundamentally improves the durability of the yarns. The results of the durability tests show that the polymer-impregnated multifilament yarns CemFil-SBR2 are probably more suitable for use in cementitious binders, as they have better alkali and hydrolysis resistance.