Characterization of the γ,α-alumina and its adsorption capability to adsorb nickel (ii) and magnesium (ii) from nickel sulfate as a result of solvent differences

Abstract

This study discusses the characteristics phase of the alumina mixture, namely the γ, α-alumina as well as its ability to adsorb the nickel (II) and magnesium (II) from nickel sulfate due to solvent differences. The γ, α-alumina was synthesized under acidic conditions (pH = 5) from poly aluminum chloride that was calcined at 800 °C by the sol-gel method. The particle size of γ, α-alumina is 15.65 μm; BET specific surface area of 104.12 m2 g−1; mesopores volume of 0.284 mL g−1; and a shape type of IV isotherm curve. Such the characteristic belongs to an adsorbent. The solution of nickel sulfate as Solution (b) has a bigger total adsorption capacity than that of the Solution (a), namely 16.46 mg L−1 and 2.49 mg L−1 respectively. The alkaline buffer formation as the ammonium hydroxide and ammonium chloride in Solution (a) may result in reducing the adsorption capability of the γ,α-alumina. The magnesium concentration of nickel sulfate in Solution (a) is smaller than that of the nickel one, namely 118.36 mg L−1 for the Mg and 486.64 mg L−1 for the Ni. However, the Mg is still more adsorbed around 29.96 mg L−1 compared to the Ni (19.80 mg L−1).