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Abstract
The electropolymerization of o-anisidine leads to the formation of a polymer which is in the same time strongly oxidized and charged in a large potential range: the poly- o-methoxyaniline (POMA). The POMA Raman features are strongly different from the polyaniline (PANI) ones; in particular a new band, absent from the PANI spectrum, prevails in a large potential range. The nature of the polymer structures obtained in function of the polarization potential is discussed from their Raman spectra. A new polymeric configuration of the oxidized/charged rings is therefore described.
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