Abstract

Metachromatic reactions of MB and AO are studied with poly(aminium phosphate)s. The main band(α) at 665 mμ and 492 mμ for MB and AO are shifted to 580 mμ and 455 mμ respectively (β-bands). The metachromatic values at different concentrations of poly(aminium phosphate)s are also reported. The dye association for MB with these polymer derivatives is investigated conductometrically as well. It is observed that MB can be at the most bind with the phosphate residue of polymer upto 1∶1 molar ratio. The polymeric nature was further established by paper chromatographic technique in Terry's, Ebel's & Pfrengle's solvents.

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