Characterization of solidified melt among materials of UO2 fuel and B4C control blade

Abstract

To predict the fundamental phase relationships in the solidified core melt of the Fukushima Daiichi Nuclear Power Plant, solidified melt samples of the various core materials [B4C, stainless steel, Zr, ZrO2, (U,Zr)O2] were prepared by arc melting. Phases and compositions in the samples were determined by means of X-ray diffraction, microscopy, and elemental analysis. With various compositions, the only oxide phase formed was (U,Zr)O2. After annealing, the stable metallic phases were an Fe-Cr-Ni alloy and an Fe2Zr-type (Fe,Cr,Ni)2(Zr,U) intermetallic compound. The borides, ZrB2 and Fe2B-type (Fe,Cr,Ni)2B, were solidified in the metallic part. Annealing at 1773 K under an oxidizing atmosphere (Ar-0.1%O2) resulted in the oxidation of U and Zr in the alloy and in ZrB2, and consequently the (Fe,Cr,Ni)2B and Fe-Cr-Ni alloy became dominant in the metallic part. The experimental phase relationships in the metallic part agreed reasonably with the thermodynamic evaluation of equilibrium phases in a simplified B4C–Fe–Zr system. The metallic Zr content in the melt was found to be a key factor in determining the phase relationships. As a basic mechanical property, the microhardness of each phase was measured. The borides, especially ZrB2, showed notably higher hardness than any other oxide or metallic phases.