Characterization of Residual Carbon in Fly Ashes from Power Plants Firing Biomass

Abstract

Fly ash samples were collected from grate fired power plant units burning mixed fuels of agricultural residues and woody biomass. The fly ashes were characterized in terms of the residual carbon mainly via nonisothermal thermogravimetric analysis (TGA) technique and loss-on-ignition (LOI) approach. TGA by heating of the fly ashes at 7 °C/min to 900 °C in air atmosphere showed three distinct peaks of weight loss in the temperature ranges of 350–530 °C, 530–660 °C, and 660–900 °C, which were confirmed to result mainly from the oxidation of residual carbon, the decomposition of calcium carbonate, and the release of alkali chlorides related species, respectively. It was shown that nonisothermal air TGA can distinguish the contribution of residual carbon oxidation to weight loss from those of the reactions of inorganic matter and, therefore, can be used as a simple technique for estimating the residual carbon content in biomass combustion fly ashes for engineering applications. The residual carbon content dete...