Abstract
Abstract The concept of size-invariant subductions has been proposed to design prochiral molecules. Thus, an even-membered homospheric orbit has been proved to be desymmetrized into an enantiospheric orbit, where the sizes of the relevant orbits remain invariant. The concept has been applied to methanes, allenes, adamantanes, and biphenyls. It has proved effective in designing a wide variety of prochiral molecules. These prochiral molecules have been shown to be extrinsic meso compounds. Intrinsic meso compounds have also been discussed as another type of prochiral molecule.
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