Characterization of Phase Change Materials Fabricated with Cross-Linked Graphene Aerogels.

Abstract

3D porous graphene aerogel exhibits a high surface area which can hold plenty of pure phase change material (PCM) into the internal space. In order to maintain the flexibility of PCM without volume shrinkage under the external force, cross-linked graphene aerogel was prepared by the cysteamine vapor method. The cross-linked graphene aerogel had a high stress–strain durability and chemical stability for infiltrating PCM to produce a form-stable PCM composite. The latent heat of PCM is one of the elements to estimate the capacity of PCM thermal energy storage (TES) during the phase transition process. The cross-linked graphene aerogel-supported PCM composite showed a great TES to be utilized in thermal-to-electrical energy harvesting. The cross-linked graphene aerogel also had an excellent mechanical property of preventing damage at a high temperature.