Characterization of mixed micelles of sodium cumene sulfonate with sodium dodecyl sulfate and cetyl trimethylammonium bromide by SANS, FTIR spectroscopy and NMR spectroscopy

Abstract

The aqueous solutions of sodium cumene sulfonate (NaCS) and its mixtures with cetyl trimethylammonium bromide (CTAB) and sodium dodecyl sulfate (SDS) are studied by Small Angle Neutron Scattering (SANS), Fourier Transform Infrared (FTIR) spectroscopy and Nuclear Magnetic Resonance (NMR) spectroscopy. The compositions of mixed micelles are determined using Rubingh's Regular Solution Theory. NaCS when added to CTAB solution leads to the formation of long rod shaped micelles with dramatic increase in the CTAB aggregation number. Its addition to SDS on the other hand results in the formation of smaller mixed micelles where parts of SDS molecules in the micelle are replaced by NaCS molecules. NaCS–SDS mixed micelles prefer elongated ellipsoidal geometry in order to accommodate short NaCS molecules. The FTIR spectroscopy results indicate enhanced ordering of CTAB tails inside the NaCS–CTAB mixed micelles with reduction in the gauche/ trans conformer ratio. Addition of NaCS to SDS on the other hand results in decreased ordering of SDS tails, as compared to SDS micelles alone. The chemical shifts observed in 1H NMR spectra of NaCS–SDS and NaCS–CTAB mixture indicate that NaCS resides near the surface of the SDS micelle.