Characterization of Li2TiO3 pebbles by graphite bed process

Abstract

Lithium titanate (Li2TiO3) is an important tritium breeder for fusion blanket concepts. In the present study, Li2TiO3 ceramic pebbles were successfully fabricated by a graphite bed process. In this process, graphite bed which had been engraved with spherical pits acted as a casting mould. Droplets of Li2TiO3 suspensions were dispersed into the spherical pits to form pebbles due to the hydrophobic nature of the graphite powder. After drying, green pebbles were sieved and sintered to produce Li2TiO3 pebbles. The fabrication process and properties of the pebbles have been investigated. The experimental results showed that the sphericity of Li2TiO3 pebbles was influenced by solid/liquid ratio and diameter. XRD results demonstrated that Li2TiO3 pebbles with high purity have been prepared by the graphite bed process. SEM revealed that the pebbles have uniform microstructure and adequate open porosity. The Li2TiO3 pebbles sintered at 1150°C have optimal properties, such as high density (about 90% TD) and high crush load (about 40N).