Characterization of heteroatom-containing species in the soluble portion from the ethanolysis of the extraction residue from Xinghe lignite by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

Abstract

The extraction residue (ER) from Xinghe lignite was subjected to ethanolysis at 300°C and the yield of ethanol-soluble portion (ESP) is 66.8wt% (daf). The ER was characterized by solid-state 13C nuclear magnetic resonance spectrometry (SS 13C NMRS) and X-ray photoelectron spectrometry (XPS), while non-basic and basic heteroatom-containing species in the ESP were analyzed by negative- and positive-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS), respectively. According to the characterization by SS 13C NMRS, the ER contains 56.6% of aromatic carbon and 37.8% of aliphatic carbon and each aromatic cluster contains 2 aromatic rings on average. The characterization by XPS suggests that OH, pyrrolic nitrogen, thiophene, and sulfoxide are important heteroatom occurrences in the ER. According to the analysis by ESI FTICRMS, the non-basic and basic species distribute in the range of molecular mass from 160 to 450u and 200 to 950u, respectively. The abundant O2 class species among the identified non-basic species could be alkanoic acids, arenediols, and arenoic acids. Non-basic N and NO classes could be pyrroles, indoles, and carbazoles with double bond equivalent (DBE) values from 1 to 16 and carbon numbers (CNs) from 7 to 28. The NOx class species dominate the basic species and span wider DBE values (4–24) and CNs (14–54). Most of these species could be attributed to quinolines (DBE⩾7), acridines (DBE⩾10), and N-heterocyclic aromatics with at least 4 rings like benzoacridine ring (DBE=13). Sulfur in the acidic classes (O3S, S2, and OS2) mainly exists in mercapto group and/or thiophene ring, while the basic OS and O2S classes may have sulfur present in thiophene sulfoxides and thiophene sulfones, respectively.