Abstract
Laboratory scale batch experiments were performed to investigate the decomposition characteristics of gaseous ozone in porous media. The decomposition rates of gaseous ozone in several solid media were determined, and the relationship of moisture content with sorbed ozone molecules was evaluated. Ozone decomposition in control and glass beads packed columns followed second-order reaction kinetics, while ozone consumption in a sand-packed column demonstrated first-order kinetics with a rate constant of 0.0109 min−1 and half-life of 1.0 h. The presence of typical metal oxides in the soil resulted in ozone consumption rates in the following order: hematite (Fe2O3) > silica-alumina (SiO2Al2O3) > alumina (Al2O3) > silica (SiO2). Ozone decomposition was highly dependent upon soil moisture content. Over 90% of the total ozone mass decomposed in the field soil with moisture content at less than 1 wt%, whereas as low as 5–15% of the total ozone mass degraded with moisture content at more than 2 wt%. In conclusion, ozone decomposition in soils was primarily controlled not only by soil organic matter but also by reactive metal oxides on the soil surface. These two factors were shown to be highly dependent upon soil moisture content.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Soil and Sediment Contamination: An International Journal
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
