Characterization of corrosion products formed on Q235 carbon steel and T2 copper in the Antarctic atmosphere

Abstract

This study delves into the intricate corrosion behavior of ferrous and non-ferrous alloys in the challenging Antarctic marine atmosphere. Despite the harsh conditions and exceptionally low anthropogenic emissions in Antarctica, materials are still susceptible to severe corrosion. The investigation focuses on two materials: Q235 carbon steel and T2 copper. Both display distinct corrosion cases between their skyward and groundward sides due to the abrasive impact of persistent strong winds carrying ice particles and grit. Electrochemical reactions at the anode and cathode drive surface corrosion processes, involving Cl− and SO42−, ultimately leading to the formation of various corrosion products. The study highlights the role of sulfur-containing aerosols, Methanesulfonic acid (MSA) and non-sea-salt sulfate (nss-SO42-) in corrosion processes, as well as the interaction between Cl− and copper in forming corrosion products. The findings emphasize the complex interplay of environmental factors like wind, ice cover, and aerosols with materials, leading to diverse corrosion products and surface transformations. Further research is crucial to gain a comprehensive understanding of corrosion challenges in extreme environments like Antarctica and to develop effective mitigation strategies.