Abstract

Abstract To address all the concerns of organic electronics device development and especially ageing issues, analytical techniques must be able to provide extremely fine characterization of the composition and thickness of layers and interfaces, while retaining appropriate spatial resolution. Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) is able to provide a detailed characterization of the in-depth composition of hybrid organic/inorganic multilayer structures which is crucial for such investigations. The study of an aged AlQ3 film after an exposition at the ambient atmosphere permitted to identify the secondary ions that are potentially indicative of the hydrolysis reaction of AlQ3. The investigation of the organic/inorganic multilayer devices by ToF-SIMS depth profiling also confirmed a confinement of the moisture in the gas barrier layer(s). It was possible to determine the moisture ratio present in the different barrier architectures to compare the efficiency of the encapsulation. In particular, the double barrier layer has shown a lower and a more localized diffusion of the moisture in the barrier which was consistent with the results of the performance of the devices and with the data reported in the literature such as water vapor transmission rate ones.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.