Abstract
Structural characterization of a stable copper(II) complex of a new, sterically constrained tetradentate ligand obtained from 2,2′-bis-(1-phenyl-3-methyl-5-t-butylthiopyrazol-4-ylmethyleneamino)biphenyl containing two imino and two thiolato donor atoms reveals a pseudotetrahedral CuN2S2 co-ordination array with a CuN2–CuS2 dihedral angle of 51.9° and appreciable S ⋯ S interaction; the electronic structure of this compound is related to that of copper centres involving the Cu–S chromophore in copper metalloproteins.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Chemical Society, Chemical Communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.