Characterization of 235U, 238U and 239Pu fission ionization chamber foils by [formula omitted] and [formula omitted]-ray spectrometry

Abstract

The masses of thin, electroplated deposits of 235U, 238U and 239Pu on titanium backings have been determined to better than 1.3% precision by employing three complementary measurement techniques: α spectrometry, 2π gas counting, and γ-ray spectrometry. A dedicated α spectrometer was designed and calibrated to allow for repeatable, high-precision measurements of the absolute α activity of a sample. The isotopic composition of the sample was determined by fitting the peaks in the α spectrum, a technique which was demonstrated to be generally consistent with mass spectrometry. Independently, the total activity of the deposits were measured in a 2π gas flow proportional counter. A detailed study of the effects of α particle straggling in the actinide deposit and α particle recoil off the sample backing material was performed. The masses of these actinide deposits were also measured via γ-ray spectrometry. We found that all three systematically independent techniques produced consistent results, and could be combined into a weighted average with further reduced uncertainty. The mass ratios of these actinide deposits were determined to better than 1% precision via α spectrometry, enabling high-precision fission cross section ratio measurements.