Characterization and relative sonocatalytic efficiencies of a new MWCNT and CdS modified TiO2 catalysts and their application in the sonocatalytic degradation of rhodamine B

Abstract

TiO2 nanoparticles modified with MWCNTs and CdS were synthesized by the sol–gel method followed by solvothermal treatment at low temperature. The chemical composition and surface structure of the CdS/CNT–TiO2 composites were investigated by X-ray diffraction, specific surface area measurements, energy-dispersive X-ray spectroscopy, transmission electron microscopy, and scanning electron microscopy. Then a series of sonocatalytic degradation experiments were carried out under ultrasonic irradiation in the presence of CNT/TiO2 and the CdS/CNT–TiO2 composites. It was found that RhB was quickly and effectively degraded under different ultrasonic conditions. As expected, the nanosized CdS/CNT–TiO2 photocatalyst showed enhanced activity compared with the non CdS treated CNT/TiO2 material in the sonocatalytic degradation of RhB. The sonocatalyst CCTb with 34.68% contents of Ti heat treated at 500°C for 1h showed the highest sonocatalytic activity. The synergistic effect of the greater surface area and catalytic activities of the composite catalysts was examined in terms of their strong adsorption ability and interphase interaction by comparing the effects of different amounts of MWCNTs and CdS in the catalysts and their roles. The mechanism of sonocatalytic degradation over the CdS/CNT modified TiO2 composites under different ultrasonic conditions was also discussed.