Characterization and preparation of conductive exfoliated graphene nanoplatelets kenaf fibre hybrid polypropylene composites

Abstract

Exfoliated graphene nanoplatelets (GNP) kenaf fiber (KF) hybrid polypropylene (PP) composites materials were prepared by melt extrusion followed by injection molding. PP/KF/MAPP/GNP composites 0–5phr were prepared and characterized using X-ray diffraction (XRD), differential scanning calorimetre (DSC), thermogravimetry analysis (TGA), heat deflection temperature (HDT), thermal mechanical analysis (TMA), Fourier transform infrared (FTIR) spectroscopy analysis, field emission scanning electron microscopy. The morphological studies revealed a homogenous dispersion of GNPs in PP/KF/MAPP/GNP up to 3phr loading after which agglomeration occurred. Flexural strength and modulus were enhanced by 70% and 98% respectively at 3phr GNPs loading which were the highest values obtained. Interestingly, the highest value for the impact strength was also recorded at 3phr loading. Thermal conductivity increased by 88%, CTE decreased by 80%, water absorption and thickness swelling decreased while HDT improved. The thermal stability of the composites were generally improved at all GNP loading with the highest at 3phr. From the overall results, it is obvious that the optimum concentration of GNPs in the PP/KF/MAPP/GNP system in terms of both mechanical and thermal properties was 3phr loading. Although, the mechanical and thermal properties of the composites were improved, the FTIR analysis did not reveal any chemical interaction between GNP and the PP/KF/MAPP system.