Abstract

Nanosized zinc stannate Zn 2 SnO 4 ( ZTO ) was synthesized via a simple hydrothermal method using sodium hydroxide NaOH as a mineralizer. Hydrothermally treated at 150, 200, and 250°C for 24 h and 48 h, the X-ray diffraction (XRD) pattern showed that highly crystalline ZTO nanostructures could be formed at 200 and 250°C. Transmission electron microscopy (TEM) images showed that ZTO nanocubes were formed at 250°C, and a sheet-like structure was found at 200°C. Raman spectra revealed that ZTO had a spinel structure and there were two Raman shift peaks at approximately 668 and 535 cm-1, which were similar to the peaks of ZTO nanowires. Furthermore, the photocatalytic activity of the ZTO samples was assessed utilizing methylene blue (MB) under ultraviolet irradiation, and the UV-Visible light absorption spectra was investigated to interpret the relationship between photocatalytic properties and light absorptivity. The sheet-like ZTO nanostructures exhibited better photocatalytic activity due to their excellent light absorption properties.

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