Abstract
The by-products of industrial 2,4,6-trinitrotoluene (TNT), including isomers of trinitrotoluene, dinitrotoluene, trinitrobenzene and dinitrobenzene were investigated using liquid chromatography–mass spectrometry (LC–MS), in order to build a profile for the characterization of TNT samples from various origins. LC–MS with atmospheric pressure chemical ionization, in the negative-ion mode, was found to be the most suitable method for this study. The characterization of TNT by the by-product profile was demonstrated on a variety of TNT samples.
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