Abstract

New R 2BaCoO 5 compounds with R  Dy, Er, Tm and Lu have been synthesized and characterized by X-ray powder diffraction. All of them are isostructural with the previously reported R 2BaCoO 5 where R  Ho, Yb and Y. They crystallize in the Sm 2BaCuO 5 structural type and belong to the Pnma space group ( Z=4). The structural differences found between Pnma-R 2BaCoO 5 oxides and other related compounds are given. The magnetic properties of the whole family of oxides (R  DyLu and Y) have been studied from magnetic susceptibility measurements, showing the presence of three-dimensional antiferromagnetic interactions at low temperatures ( T N < 5 K) for most of these oxides.

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