Abstract
In this paper, Co–Al-layered double-metal hydroxides (CAD-LDHs) were synthesized by co-precipitation in the presence of dodecylsulfate (DDS) and characterized by XRD, FT-IR, TG–DSC, SEM. In addition, their frictional features were evaluated by four-ball friction tester, gear tester and air compressor. The results showed that synthesized CAD-LDHs have a hexagonal platelet morphology. Most crystallites have a disk diameter of around 150–250nm and a thickness of about 20nm, with a0=b0=0.31nm, c0=8.33nm, d-spacing=2.78nm and gallery height=2.30nm. The specific surface area is 78m2/g. DDS anions entered the interlayer of LDHs and were perpendicular to the LDH layer in a monolayer array. As a lubricant, CAD-LDH powder has excellent dispersability and suspension stability in the lubrication oil, and can significantly reduce friction coefficient (50.7%) and wear of friction pairs (17.9%). At the same time, they can reduce the temperature of lubrication oil (6.1%) and power consumption of driving motor (2.6–6.8%). Accordingly, CAD-LDHs may broadly be used as lubrication and anti-frictional materials.
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