Abstract
The morphology of diamond surface etched by molten potassium nitrate was investigated and the formantion mechanism of etched pits was disscussed. The inverted pyramid and square-shaped pits were formed on the {111} face and {100} face of diamond particles, respectively. The size and depth of etching pits on {100} face were apparently smaller than that of {111} face, which suggests {100} face has higher stability due to the role of oxygen functional groups absorb on the structure. At a low etching temperature (600°C), square-shaped pits were firstly formed on {100} face and then gradually changed into octagon shape with the increasing of etching time. The change of shape can be attributed to the configuration of atomic on {100} face of diamond and the change of oxygen partial in molten salt during the etching process. When etch temperature up to 700°C, the edges direction of the preferentially formed square shape pit became an angle of 45°with the edges of later formed square shape pit which indicated that partial oxygen pressure can effect stability of diamond surface and etching direction.
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