Characterization and Catalytic Activity of Acid-Treated, Size-Fractionated Smectites

Abstract

Five layered silicates in which the octahedral sheet contained differing amounts of Al, Mg, Fe, and Li were acid leached using acid concentrations and treatment temperatures selected to produce materials in which the octahedral sheet was depopulated in a controlled, stepwise (yet comparable) manner. SAz-1 and JP are dioctahedral smectites with octahedral compositions rich in Mg and Al, respectively. SWa-1 is a ferruginous smectite and ST an iron-rich beidellite. The fifth mineral was a trioctahedral hectorite which contains almost exclusively octahedral Mg. The Bronsted acidity and catalytic activity of the resulting materials were highest for the samples prepared with the mildest acid treatments but decreased as the octahedral sheet became increasingly depleted. Only the hectorite exhibited no catalytic activity despite the proven existence of Bronsted acid sites. The elemental composition of the starting material did not appear to make a significant contribution to the catalytic activity for the chosen ...