Characteristics of transmission light in tetracycline hydrochloride polluted wastewater and the response of g-C3N4 under different transmission spectral range during the photodegradation process

Abstract

The purification efficiency of the contaminants in the process of photocatalysis is influenced by the co-function of catalytic activity of materials, aquatic environment conditions and characteristics of transmission light. Here, tetracycline hydrochloride (TC-HCl) was introduced as the target pollutant, and the effects of different depths and TC-HCl concentrations on the transmission light intensity and spectral distribution were explored. The results show that incident light decreases with the increase of depth and pollutant concentration. The increase of depth influences the irradiance greatly, however, increase of concentration mainly lead to the narrow of transmission spectral range in the underwater field. The coupling relationship among pollutants, transmission spectral characteristics and photocatalytic reaction efficiency was discussed. Results show that the reduction of the underwater spectral range will reduce the effective response area of the material significantly, which directly leads to the reduction of pollutant removal efficiency in the degradation process. Aiming at different aquatic environment, photocatalytic materials with appropriate response spectral range should be selected to improve the light absorption ability, so that the removal efficiency can be improved significantly.