Characteristics of the chromophoric dissolved organic matter of urban black-odor rivers using fluorescence and UV-visible spectroscopy.

Abstract

Urban black-odor water (BOW) is a typical phenomenon seen in the urban water environment; it is caused by excessive pollution by organic matter and other pollutants, such as nitrogen and phosphorous. Chromophoric dissolved organic matter (CDOM) is a major optical fraction of dissolved organic matter. In this study, optical properties and components of CDOM were obtained from 178 river samples collected from five cities in China, the sample were investigated using absorption and fluorescence spectroscopy. The collected included 89 ordinary water (OW) samples, 63 mild BOW (MBOW), and 26 heavy BOW (HBOW) samples. Significant differences were found in the absorption spectra of the HBOW, MBOW, and OW samples, particularly in their optical parameters (the slope of the spectrum (S275-295), and the ratio of two absorption coefficients of CDOM (E2:E3)). Additionally, the fluorescence intensity of the humic acid-like component (F5) and soluble microbial by product-like component (F4) obtained via the fluorescence regional integration (FRI) method were 3 and 4.2 times higher in HBOW than in OW, respectively; this could be used as an indicator to distinguish OW from BOW in urban rivers. The results obtained using the redundancy method and the strong negative correlation between F4 and dissolved oxygen (DO) (r=- 0.56) suggested that the composition of CDOM could change significantly under different urban water environments (p<0.01). Different correlations were also found between F5, and a355, E2:E3, S275-295 in different BOW levels, suggesting that the optical parameters of CDOM were mainly determined by the polluted organic matter originating from terrestrial sources with large molecular humic acid-like compounds; optical parameter a355 could distinguish BOW from OW. These findings are conducive in understanding the dynamics of organic matter pollution and to discover the composition and optical properties of the CDOM in urban BOW and OW, thereby providing an effective method for tracking the spatial characteristics of BOW in urban rivers using remote sensing technologies in areas with multiple sources of pollution.