Abstract

CH 4/ CF 4 mixture gas plasmas were studied by a heated double probe method (HDPM) and the relation among plasma states, chemical reaction in the plasma and the characteristics of deposited films was investigated. Electron temperature determined by HDPM had a sharp minimum at the flow rate ratio of CH 4/ CF 4 = 1.8. At high discharge current (200 mA), a hard carbon film with amorphous structure was formed on various kinds of substrates. From the plasma mass spectra, HF molecules were found to play an important role in the plasma reaction and a stoichiometric reaction model was proposed. The unusual variation of the electron temperature was discussed on the basis of the reaction model.

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