Characteristics of air pollution complex in a typical chemical industrial development zone in eastern China

Abstract

VOCs (volatile organic compounds) have an important impact on the atmospheric environment, climate and human health. In a typical chemical industrial development zone in eastern China, 123 kinds of VOCs were on-line monitored simultaneously at three sites using the GC-FID/MS system for one year. The seasonal and diurnal variations of composition and concentration of VOCs were compared and analyzed systematically. The VOCs features existed significant differences at the three sites, which were greatly affected by the types and emissions of surrounding enterprises. The alkanes appeared as the major pollutants at the site adjacent to petrochemical processing enterprises (site A), while OVOCs were the majority at the other two sites, which were around by the fine chemical enterprises (site B and C). The TVOC concentrations presented seasonal differences at the three sites, which showed higher values in summer (468.6 μg/m3) at site A, in winter (409.2 μg/m3) at site B，and in autumn (298.9 μg/m3) at site C, respectively. The isopentane (16.8%) and ethylene oxide (17.9%) made up the largest proportion of the VOCs at site A and B, respectively. While it was more susceptible to the effects of dichloromethane, 1,2-dichloroethane and chloromethane at site C. Three pollution events of ethylene oxide, isopentane and dichloromethane were analyzed and traced based on the prevailing wind and the change of concentration at the three sites. Further analysis of the impact of VOCs on the formation of secondary pollutants of O3 and PM2.5 found that the contribution of local O3 (28.1 %) in summer was significantly larger in the study area than that in non-industrial area. The multiphase chemical reactions were more likely to occur in autumn, which promoted the formation of secondary PM2.5, showing the correlation coefficient of 0.73 between the secondary organic aerosol formation potential of VOCs and PM2.5.