Characteristics and mechanism of phosphate removal by lanthanum modified bentonite in the presence of dissolved organic matter

Abstract

Lanthanum modified bentonite (LMB) is a widely used adsorbent for removing inorganic phosphorus from polluted water to prevent eutrophication. However, its efficiency can be affected by various environmental factors, including dissolved organic matter (DOM), which is still unclear. In this study, we systematically explored the influence of model DOMs, including HA, bovine serum albumin (BSA), and sodium alginate (SA), on phosphate adsorption by LMB, as well as to elucidate the underlying adsorption mechanisms. Our results showed that only HA had a significant effect on phosphate adsorption by LMB, causing inhibition. When three DOMs were mixed with phosphate in different proportions and DOM was mainly HA, the performance of phosphate adsorption on LMB became worse, while BSA can slightly offset this impact. The kinetics of HA and phosphate adsorption on LMB followed the pseudo-second-order kinetic model, and isotherms fitted the Langmuir model, with a maximum adsorption capacity of 5.7 mg g−1 for P and 12 mg g−1 for HA. However, when HA and phosphate were mixed based on their Qm, a C/P molar ratio of 5.35, LMB preferentially adsorbed phosphate. HA invasion was also disadvantageous for phosphate removal by LMB, in which P adsorption was less efficient at low-concentrations. However, during co-adsorption the adsorption capacity for HA was higher. With a secondary addition of higher levels of P, both pollutants were adsorbed more effectively. In the natural water experiment, phosphate concentration decreased with increasing shaking time, while the UV254 value showed a downward trend, indicating that LMB also adsorbed HA. Characterization results showed that La and phosphate formed LaPO4 precipitation, forming La–O–P inner-sphere complexes as the main mechanism of phosphate removal by LMB. La and HA formed La-HA complexes, with O–CO bonds from HA competing for lanthanum with phosphate. Despite HA obstructing pores from adsorbent, LMB still maintained a good binding ability with phosphate. It may form La–P-HA ternary complexes during adsorption to keep HA adsorption amount.